Our group focuses on the synthesis and application of orgnaic-inorganic hybrid materials.

A typical TEM picture of the material we synthesized

 

The strategies involve the supramolecular synthesis of periodic mesoporous organosilicas, sol-gel synthesis of hybrid organic-inorganic armorphous materials, and surface organo-metallic synthesis of organometallic complex functionalized materials as well.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 


2017   2016  2015   2014   2013   2012   2011   2010   2009   2008   2007   2006   2005  2004 2003   2002


(20) Peng Wang, Shiyang Bai1, Jiao Zhao, Panpan Su, Prof. Qihua Yang*, Prof. Can Li*Bifunctionalized Hollow Nanospheres for the One-Pot Synthesis of Methyl Isobutyl Ketone from Acetone ChemSusChem 5, 12,2390–2396

(19) Bo Li, Shiyang Bai, Xuefeng Wang, Mingmei Zhong, Qihua Yang*, Can Li*Hydration of Epoxides on [CoIII(salen)] Encapsulated in Silica-BasedNanoreactors Angew. Chem. Int. Ed. 2012, 51(46),11517–11521

(18) WANG Peng, BAI Shiyang, LI Bo, YANG Qihua*Immobilization of Vanadyl Acetylacetonate on Amino Functionalized HollowSilica Nanospheres and Its Catalytic Performance for Selective Oxidation of Thioanisole Chin. J. Catal., 2012, 33: 1689–1695

(17) Jia Liu , Shiyang Bai , Qianru Jin , Can Li and Qihua YangEnhanced thermostability of enzymes accommodated in thermo-responsivenanopores Chem. Sci., 2012, 3 (12), 3398 - 3402

(16) Xiaobo Li , Xiao Liu , Yan Yang , Jiao Zhao , Can Li and Qihua YangEntrapment of Metal Nanoparticles within Nanocages of Mesoporous Silicas Aidedby Co-surfactant J. Mater. Chem., 2012, 22 (39), 21045 - 21050

(15) Qi Sun, Xiangju Meng, Xiao Liu, Xiaoming Zhang, Yan Yang, Yang Qihua, Feng-Shou Xiao
Mesoporous Cross-Linked Polymer Copolymerized with Chiral BINAP Ligand Coordinated to Ruthenium Species as an Efficient Heterogeneous Catalyst for Asymmetric Hydrogenation
Chem. Commun. 2012 48, 10505-10507

(14) Panpan Su, Liang Jiang, Jiao Zhao, Jingwang Yan, Can Li* and Yang Qihua*Mesoporous graphitic carbon nanodisks fabricated via catalytic carbonization of Chem. Commun. 2012,48, 8769-8771

(13) Yan Yang, Xiao Liu, Xiaobo Li, Jiao Zhao, Shiyang Bai, Jian Liu,* and Qihua Yang*Yolk-Shell Nanoreactor with Basic Core and Acidic Shell for Cascade Reactions. Angew. Chem. Int. Ed., 2012, 51(36), 9164–9168,

(12) Shiyang Bai, Bo Li, Juan Peng, Xiaoming Zhang, Qihua Yang* and Can Li*Promoted activity of Cr(Salen) in a nanoreactor for kinetic resolution of terminal epoxides. Chem. Sci., 2012,3, 2864-2867

(11) Bo Li, Fei Li, Shiyang Bai, Zhijun Wang, Licheng Sun, Qihua Yang* and Can Li*Oxygen evolution from water oxidation on molecular catalysts confined in the nanocages of mesoporous silicas. Energy Environ.Sci. 2012,5, 8229-8233

(10) Xiaobo Li, Xian-Yang Quek, D.A.J. Michel Ligthart, Meiling Guo, Yi Zhang, Can Li, Qihua Yang*, Emiel J.M. Hensen*. CO–PROX Reactions on Copper Cerium Oxide Catalysts Melt Infiltration. Appl. Catal. B 123–124 (2012) 424– 432.

(9) Jia Liu, Shiyang Bai, Qianru Jin, Hua Zhong, Can Li*, Qihua Yang* Improved catalyticperfermance of Lipase accomodated in the mesoporous silicas with polymer-modified microenvironment. Langmuir, 2012, 28, 9788-9796.

(8) Jiao Zhao, Fuqing Wang, Panpan Su, Mingrun Li, Jian Chen, Qihua Yang* and Can Li* ZnMn2O4 nanoplate assemblies fabricated via "escape-by-crafty-scheme" strategy. Journal of Materials Chemistry, 2012, 22, 13328-13333.

(7) Lei Zhang, Shuaibin Wu, Can Li and Qihua Yang*. Facile synthesis of hybrid hollow mesoporous nanospheres with high content of interpenetrating polymers for size-selective peptides/proteins enrichment. Chem. Commun., 2012,48, 4190-4192.

(6) Jiao Zhao, Panpan Su, Yaopeng Zhao, Mingrun Li, Yan Yang, Qihua Yang* and Can Li*. Systematic morphology and phase control of Mg-ptcda coordination polymers by Ostwald ripening and self-templating. Journal of Materials Chemistry, 2012, 22, 8470-8475.

(5) Jiao Zhao, Mingrun Li, Junliang Sun, Leifeng Liu, Panpan Su, Qihua Yang* and Can Li*. Metal-oxides nanoparticles with desired morphology inherited from coordination-polymer precursors. Chemistry-A European Journal, 2012, 18, 3163-3168.

(4) Xiaobo Li, Xiao Liu, Yi Ma, Mingrun Li, Jiao Zhao, Hongchuan Xin, Lei Zhang, Yan Yang, Can Li,Qihua Yang*. Engineering the Formation of Secondary Building Blocks within the Hollow Interiors. Advanced Materials,2012, 24, 1424-1428.

(3) Xiao Liu, Shiyang Bai, Yan Yang, Bo Li, Bing Xiao, Can Li and Qihua Yang*. Enantioselective carbonyl–ene reaction on BINOLate/titanium catalyst encapsulated in magnetic nanoreactors Chem. Commun., 2012, 48, 3191-3193.

(2) Jiao Zhao, Xin Shi, Guanna Li, Xiuli Wang, Can Li*, Qihua Yang*. Zinc and cadmium coordination polymers assembled with 2,2'-bipyridine and bithiophenedicarboxylic acid: Effect of metal ions on the conformation of ligand. Inorganica Chimica Acta. 2012, 383, 185-189.

(1) Shiyang Bai,Jian Liu, Jinsuo Gao, Qihua Yang*, Can Li*. Hydrolysis conrolled Synthesis of amine-functionalized hollow ethane–silica nanospheres as adsorbents for CO2 capture. Microporous and Mesoporous Mater. 2012,151,474-480

 

State Key Laboratory of Catalysis, SKLC
Dalian Institute of Chemical Physics,DICP
Chinese Academy Sciences, CAS
TEL: +86-411-84379552 FAX: 86-411-84694447