Our group focuses on the synthesis and application of orgnaic-inorganic hybrid materials.

A typical TEM picture of the material we synthesized

 

The strategies involve the supramolecular synthesis of periodic mesoporous organosilicas, sol-gel synthesis of hybrid organic-inorganic armorphous materials, and surface organo-metallic synthesis of organometallic complex functionalized materials as well.

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 


2017   2016  2015   2014   2013   2012   2011   2010   2009   2008   2007   2006   2005  2004 2003   2002


(17) D. Jiang, J. Gao, Q. H. Yang*, C. Li* Large Pore Mesoporous Ethane-silicas as Efficient Heterogeneous Asymmetric Catalysts Studies in Surface Science and Catalysis , 2007, 170

(16) C. M. Li, J. Liu, X. Shi, J. Yang, and Q. H. Yang* Periodic Mesoporous Organosilicas with 1,4-Diethylenebenzene in the Mesoporous Wall: Synthesis, Characterization, and Bioadsorption Properties J. Phys. Chem. C 2007, 111, 10948-10954.

(15) G. Zhu, Q. H. Yang* and C. Li* Synthesis of Periodic Mesoporous Ethanesilica and Its Application in High Performance Liquid Chromatography Chin. J. Chrom., 2007, 25, 505-508.

(14) X. Shi, J. Liu, C. M. Li, Q. H. Yang* Pore-Size Tunable Mesoporous Zirconium Organophosphonates with Chiral L-Proline for Enzyme Adsorption Inorganic Chemistry 2007, 46, 7944 –7952.

(13) H. Yang, L. Zhang, L. Zhong, Q. H. Yang*, C. Li* Enhanced Cooperative Activation Effect in the Hydrolytic KineticResolution of Epoxides on [Co(salen)] Catalysts Confined in Nanocages Angew. Chem. Int. Ed. 2007, 46, 6861 –6865.

(12) G. Zhu, Q. H. Yang*, H. Zhong, D. Jiang, C. Li* A Potential Chiral Stationary Phases: Phase Transformation of the Periodic Mesoporous Organosilicas Assisted by Organotrialkoxysilane Journal of Physical Chemistry B 2007, 111, 8027-8033.

(11) D. Jiang, J. Gao, J. Yang , W. Su, Q. H. Yang*, C. Li* Mesoporous Ethane-silicas Functionalized with trans -(1R,2R)-Diaminocyclohexane: Relation between Structure and Catalytic Properties in Asymmetric Transfer Hydrogenation Microporous and Mesoporous Materials , 2007, 105, 204-210.

(10) J. Liu, C. M. Li, Q. H. Yang*, J. Yang, C. Li Morphological and Structural Evolution of Mesoporous Silicas in a Mild Buffer Solution and Lysozyme Adsorption Langmuir 2007, 23, 7255-7262.(Cover Paper)

(9) L. Zhang, H. C. L. Abbenhuis, Q. H. Yang*, Y. M. Wang, P. C. M. M. Magusin, B. Mezari, R. A. van Santen,* C. Li* Mesoporous Organic-Inorganic Hybrid Materials Built Using Polyhedral Oligomeric Silsesquioxane Blocks Angew. Chem. Int. Ed. 2007, 46, 5003 –5006

(8) J. Liu, Q. H. Yang*, X.S. Zhao, L. Zhang Pore size control of mesoporous silicas from mixtures of sodium silicate and TEOS Microporous and Mesoporous Materials 2007, 106, 62-67.

(7) G. Zhu, D. Jiang, Q. H. Yang*, J. Yang, C. Li* A Potential Chiral Stationary Phases: Bifunctionalized Mesoporous Organosilica Spheres Containing trans-(1R,2R)-Diaminocyclohexane in the Pore Journal of Chromatography A 2007, 1149, 219-227.

(6) H. Yang, L. Zhang, W. Su, Q. H. Yang*, C. Li* Asymmetric ring-opening of epoxides on chiral Co(Salen) catalyst synthesized in SBA-16 through the "ship in a bottle" strategy ournal of Catalysis 2007, 248, 204–212

(5) H. Yang, J. Li, J. Yang, Z. Liu, Q. H. Yang*, C. Li* Asymmetric reactions on chiral catalysts entrapped within a mesoporous cage Chemical Communications, 2007, 1086-1088

(4) J. Liu, Q. H. Yang*, L. Zhang, D. Jiang, X. Shi, J. Yang, H. Zhong, C. Li* Thioether-bridged Mesoporous Organosilicas: Mesophase Transformation Induced by the Bridged Organosilane Precursor Advanced Functional Materials, 2007, 17, 569-576

(3) L. Zhang, H. C. L. Abbenhuis, G. Gerritsen, N. N?Bhriain, P. C. M. M. Magusin, B. Mezari, W. Han, R. A. van Santen, Q. H. Yang, C. Li An Efficient Hybrid, Nanostructured, Epoxidation Catalyst: Titanium Silsesquioxane-Polystyrene Copolymer Supported on SBA-15 Chemistry: A European Journal 2007, 13, 1210-1221

(2) H. Zhong, G. Zhu, J. Yang, P. Wang, Q. H. Yang* Periodic mesoporous hybrid monolith with hierarchical macro–mesopores Microporous and Mesoporous Materials 2007, 100, 259-267

(1) C. M. Li, J. Yang, X. Shi, J. Liu, Q. H. Yang* Synthesis of SBA-15 type mesoporous organosilicas with diethylenebenzene in the framework and post-synthetic framework modification Microporous and Mesoporous Materials 2007, 98, 220-226

 

State Key Laboratory of Catalysis, SKLC
Dalian Institute of Chemical Physics,DICP
Chinese Academy Sciences, CAS
TEL: +86-411-84379552 FAX: 86-411-84694447